Capital Bolivia is a country located in South America. It is bordered by Brazil, Paraguay, Argentina, Chile, and Peru. The capital of Bolivia is Sucre, which has five letters in its name. Oruro is another city in Bolivia, also with five letters in its name. Paz is a city in Bolivia with three letters in its name, and Oso is another city with three letters in its name. All four cities are important to the country of Bolivia and have played a role in its history.