Time for Vespers is a term used to refer to the EVENING prayer service in the Catholic Church. It is usually held around 6 pm and is the last of the seven canonical hours of the day. The term 'Time for Vespers' can also be used to refer to the time of day when the service is held. The crossword solution for this term is EVENING, which is an appropriate word to describe the time of day when the service is held.