The crossword solutions for the term MADAM SECRETARY STAR are LEONI, which is the surname of the actress who plays the lead role in the American political drama television series 'Madam Secretary'. The series follows Elizabeth McCord, a former CIA analyst and political science professor, who is suddenly appointed as the United States Secretary of State. The actress, Tea Leoni, portrays the character of Elizabeth McCord and has been praised for her performance in the show.