The term 'Like 007' is a reference to the fictional British spy James Bond, who is known for his SUAVE and URBANE demeanor. The crossword solutions for this term are 'URBANE' (6 letters) and 'SUAVE' (5 letters). URBANE means having an elegant or sophisticated manner, while SUAVE means having a smooth, polite, and charming manner. Both words describe the character of James Bond, who is known for his debonair attitude and ability to handle any situation with grace and poise.