The crossword solution for the term 'Liberia's Capital' is Monrovia, which is an 8-letter word. Monrovia is the capital and largest city of Liberia, a country located on the West African coast. It is the economic and financial center of the country and is home to many government offices and organizations. Monrovia was founded in 1822 by freed American slaves and named after U.S. President James Monroe.