The term CHILEAN CAPITAL can be solved by two crossword solutions: LIMA (4 letters) and SANTIAGO (8 letters). LIMA is the capital of Peru, located on the country's central coast. It is the largest city in the country and is home to over 10 million people. Santiago is the capital of Chile, located in the central valley of the country. It is the largest city in Chile and is home to over 6 million people.