The term '007 Film' refers to the James Bond film series, which began in 1962 with the release of 'Dr. No'. The 10-letter solution to this crossword is 'Goldfinger', which was the third installment in the series and released in 1964. It starred Sean Connery as James Bond and was directed by Guy Hamilton. The film was a huge success and is widely considered one of the best Bond films ever made.